Cause
Possibility 1
You placed a pin in the schematic without connecting it to a component.
Possibility 2
In the plugs navigator you have pre-defined a pin or a plug with several pins by means of the New or New functions popup menu item.
Solution
Regarding option 1
Connect at least one of the symbol connection points of the placed pin to a component. Refresh the connections and then start a new check run.
Regarding option 2
Place the pin or the pins of the plug in the schematic and proceed for each pin as described in section "Regarding option 1".